Chile
Formed: 1895 Manager: Juan Antonio Pizzi [ESP]
| Number | Name | Nat | Pos | Height | Weight | Date of Birth | Birth Place | Current Club |
| 1 | Claudio Bravo | CHI | G | 1.84 | 84 | 13-04-83 | Viluco | Barcelona |
| 2 | Eugenio Mena | CHI | D | 1.71 | 73 | 18-07-88 | Viña del Mar | São Paulo (On Loan) |
| 3 | Enzo Roco | CHI | D | 1.88 | 82 | 16-08-92 | Santiago | Espanyol (On Loan) |
| 4 | Mauricio Isla | CHI | D | 1.76 | 72 | 12-06-88 | Buin | Marseille (On Loan) |
| 5 | Francisco Silva | CHI | M | 1.78 | 75 | 11-02-86 | Santiago | Chiapas |
| 6 | José Pedro Fuenzalida | CHI | M | 1.70 | 67 | 22-02-85 | Santiago | Universidad Católica |
| 7 | Alexis Sánchez | CHI | F | 1.68 | 62 | 19-12-88 | Tocopilla | Arsenal |
| 8 | Arturo Vidal | CHI | M | 1.81 | 74 | 22-05-87 | Santiago | Bayern Munich |
| 9 | Mauricio Pinilla | CHI | F | 1.87 | 78 | 04-02-84 | San Bernardo | Atalanta |
| 10 | Pablo Hernández | CHI | M | 1.84 | 79 | 24-10-86 | Capital Federal | Celta Vigo |
| 11 | Eduardo Vargas | CHI | F | 1.73 | 74 | 20-11-89 | Santiago | 1899 Hoffenheim |
| 12 | Cristopher Toselli | CHI | G | 1.80 | 75 | 15-06-88 | Antofagasta | Universidad Católica |
| 13 | Erick Pulgar | CHI | M | 1.86 | 83 | 15-01-94 | Antofagasta | Bologna |
| 14 | Mark González | CHI | M | 1.75 | 70 | 10-07-84 | Durban | Sport Recife |
| 15 | Jean Beausejour | CHI | M | 1.79 | 80 | 01-06-84 | Santiago | Colo-Colo |
| 16 | Nicolás Castillo | CHI | F | 1.77 | 76 | 14-02-93 | Santiago | Universidad Católica (On Loan) |
| 17 | Gary Medel | CHI | D | 1.72 | 71 | 03-08-87 | Santiago | Internazionale |
| 18 | Gonzalo Jara | CHI | D | 1.78 | 77 | 29-08-85 | Santiago | Universidad de Chile |
| 19 | Fabián Orellana | CHI | F | 1.69 | 68 | 27-01-86 | Santiago | Celta Vigo |
| 20 | Charles Aránguiz | CHI | M | 1.72 | 67 | 17-04-89 | Santiago | Bayer Leverkusen |
| 21 | Marcelo Díaz | CHI | M | 1.66 | 64 | 30-12-86 | Santiago | Celta Vigo |
| 22 | Edson Puch | CHI | M | 1.68 | 72 | 09-04-86 | Iquique | LDU Quito |
| 23 | Johnny Herrera | CHI | G | 1.83 | 78 | 09-05-81 | Angol | Universidad de Chile |