Spain
Formed: 1913 Manager: Vicente del Bosque
| Number | Name | Nat | Pos | Height | Weight | Date of Birth | Birth Place | Current Club |
| 1 | Iker Casillas | ESP | G | 1.85 | 79 | 20-05-81 | Madrid | Real Madrid |
| 2 | Raúl Albiol | ESP | D | 1.87 | 74 | 04-09-85 | Valencia | Valencia |
| 3 | Gerard Piqué | ESP | D | 1.92 | 85 | 02-02-87 | Barcelona | Barcelona |
| 4 | Carlos Marchena | ESP | D | 1.83 | 78 | 31-07-79 | Las Cabezas | Valencia |
| 5 | Carles Puyol | ESP | D | 1.78 | 80 | 13-04-78 | La Pobla de Segur | Barcelona |
| 6 | Pablo Hernández | ESP | M | 1.73 | 64 | 11-04-85 | Castellón | Valencia |
| 7 | David Villa | ESP | F | 1.75 | 69 | 03-12-81 | Langreo | Valencia |
| 8 | Xavi | ESP | M | 1.70 | 68 | 25-01-80 | Terrassa | Barcelona |
| 9 | Fernando Torres | ESP | F | 1.86 | 78 | 20-03-84 | Madrid | Liverpool |
| 10 | Cesc Fàbregas | ESP | M | 1.77 | 69 | 04-05-87 | Arenys de Mar | Arsenal |
| 11 | Joan Capdevila | ESP | D | 1.82 | 78 | 03-02-78 | Tarrega | Villarreal |
| 12 | Sergio Busquets | ESP | M | 1.89 | 73 | 16-07-88 | Sabadell | Barcelona |
| 13 | Diego López | ESP | G | 1.96 | 88 | 03-11-81 | Paradela | Villarreal |
| 14 | Xabi Alonso | ESP | M | 1.83 | 75 | 25-11-81 | Tolosa | Liverpool |
| 15 | Sergio Ramos | ESP | D | 1.83 | 73 | 30-03-86 | Camas | Real Madrid |
| 16 | Fernando Llorente | ESP | F | 1.95 | 94 | 26-02-85 | Iruñea | Athletic Bilbao |
| 17 | Dani Güiza | ESP | F | 1.80 | 80 | 17-08-80 | Jerez de la Frontera | Fenerbahçe |
| 18 | Albert Riera | ESP | M | 1.88 | 83 | 15-04-82 | Manacor | Liverpool |
| 19 | Álvaro Arbeloa | ESP | D | 1.83 | 76 | 17-01-83 | Salamanca | Liverpool |
| 20 | Santi Cazorla | ESP | M | 1.68 | 66 | 13-12-84 | Lugo de Llanera | Villarreal |
| 21 | David Silva | ESP | M | 1.70 | 67 | 08-01-86 | Arguineguín | Valencia |
| 22 | Juan Mata | ESP | F | 1.70 | 63 | 28-04-88 | Burgos | Valencia |
| 23 | Pepe Reina | ESP | G | 1.88 | 92 | 31-08-82 | Madrid | Liverpool |